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Cited by 8,286

The DOI matches its Crossref record.

Spin Diffusion Measurements: Spin Echoes in the Presence of a Time-Dependent Field Gradient

Stejskal, E. O., Tanner, J. E.·1965·The Journal of Chemical Physics
DOI 10.1063/1.1695690
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Abstract

A derivation is given of the effect of a time-dependent magnetic field gradient on the spin-echo experiment, particularly in the presence of spin diffusion. There are several reasons for preferring certain kinds of time-dependent magnetic field gradients to the more usual steady gradient. If the gradient is reduced during the rf pulses, H1 need not be particularly large; if the gradient is small at the time of the echo, the echo will be broad and its amplitude easy to measure. Both of these relaxations of restrictions on the measurement of diffusion coefficients by the spin-echo technique serve to extend its range of applicability. Furthermore, a pulsed gradient can be recommended when it is critical to define the precise time period over which diffusion is being measured. The theoretical expression derived has been verified experimentally for several choices of time dependent magnetic field gradient. An apparatus is described suitable for the production of pulsed gradients with amplitudes as large as 100 G cm−1. The diffusion coefficient of dry glycerol at 26°±1°C has been found to be (2.5±0.2)×10−8 cm2 sec−1, a value smaller than can ordinarily be measured by the steady gradient method.

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Research works printed but not linked: 13

  1. 1950, Phys. Rev., 80, 580, 10.1103/PhysRev.80.580 · DOI
  2. 1953, Phys. Today, 6, 4, 10.1063/1.3061075 · DOI
  3. 1954, Phys. Rev., 94, 630, 10.1103/PhysRev.94.630 · DOI
  4. 1961, J. Chem. Phys., 34, 2057, 10.1063/1.1731821 · DOI
  5. 1963, Ber. Bunsenges. Physik. Chem., 67, 336, 10.1002/bbpc.19630670312 · DOI
  6. 1963, J. Phys. Chem., 67, 1365, 10.1021/j100800a509 · DOI
  7. 1955, J. Appl. Phys., 26, 1324, 10.1063/1.1721903 · DOI
  8. 1956, Phys. Rev., 104, 563, 10.1103/PhysRev.104.563 · DOI · Paper page
  9. 1963, Rev. Sci. Instr., 34, 971, 10.1063/1.1718665 · DOI
  10. 1958, Rev. Sci. Instr., 29, 55, 10.1063/1.1716004 · DOI
  11. 1958, Phys. Rev., 111, 1201, 10.1103/PhysRev.111.1201 · DOI · Paper page
  12. 1956, Chem. Rev., 56, 387, 10.1021/cr50009a001 · DOI
  13. 1959, J. Chem. Phys., 31, 1555, 10.1063/1.1730651 · DOI

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Metadata

Authors
Stejskal, E. O., & Tanner, J. E.
Venue
The Journal of Chemical Physics
Publisher
AIP Publishing
Published
1965-01-01
Volume
42
Issue
1
Pages
288-292
ISSN
  • 0021-9606 (ISSN-L)
  • 1089-7690
DOI
10.1063/1.1695690
OpenAlex
W2084761689
Cited by
8,286
References
0
FWCI
4.54
Type
journal article
Language
en
Open access
closed

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.