Electrochemical reduction of carbon dioxide to multicarbon (C2+) products: challenges and perspectives

Progress and perspectives of electrochemical CO2 reduction on copper in aqueous electrolyte

Nitopi, S., Bertheussen, E., Scott, S. B., Liu, X., Engstfeld, A. K., Horch, S., Seger, B., Stephens, I. E. L., Chan, K., Hahn, C., et al. (2019) · Chemical Reviews · doi:10.1021/acs.chemrev.8b00705 · Cited by 5,223

Covalent organic frameworks comprising cobalt porphyrins for catalytic CO 2 reduction in water

Lin, S., Diercks, C. S., Zhang, Y.-B., Kornienko, N., Nichols, E. M., Zhao, Y., Paris, A. R., Kim, D., Yang, P., Yaghi, O. M., et al. (2015) · Science · doi:10.1126/science.aac8343 · Cited by 2,644

CO 2 electroreduction to ethylene via hydroxide-mediated copper catalysis at an abrupt interface

Dinh, C.-T., Burdyny, T., Kibria, M. G., Seifitokaldani, A., Gabardo, C. M., García de Arquer, F. P., Kiani, A., Edwards, J. P., De Luna, P., Bushuyev, O. S., et al. (2018) · Science · doi:10.1126/science.aas9100 · Cited by 2,515

Electroreduction of carbon monoxide to liquid fuel on oxide-derived nanocrystalline copper

Li, C. W., Ciston, J., & Kanan, M. W. (2014) · Nature · doi:10.1038/nature13249 · Cited by 1,728

General Techno-Economic Analysis of CO 2 Electrolysis Systems

Jouny, M., Luc, W., & Jiao, F. (2018) · Industrial & Engineering Chemistry Research · doi:10.1021/acs.iecr.7b03514 · Cited by 1,628

Accelerated discovery of CO2 electrocatalysts using active machine learning

Zhong, M., Tran, K., Min, Y., Wang, C., Wang, Z., Dinh, C.-T., De Luna, P., Yu, Z., Rasouli, A. S., Brodersen, P., et al. (2020) · Nature · doi:10.1038/s41586-020-2242-8 · Cited by 1,531

CO 2 electrolysis to multicarbon products at activities greater than 1 A cm −2

García de Arquer, F. P., Dinh, C.-T., Ozden, A., Wicks, J., McCallum, C., Kirmani, A. R., Nam, D.-H., Gabardo, C., Seifitokaldani, A., Wang, X., et al. (2020) · Science · doi:10.1126/science.aay4217 · Cited by 1,517

Electrocatalytic reduction of CO2 to ethylene and ethanol through hydrogen-assisted C-C coupling over fluorine-modified copper

Ma, W., Xie, S., Liu, T., Fan, Q., Ye, J., Sun, F., Jiang, Z., Zhang, Q., Cheng, J., & Wang, Y. (2020) · Nature Catalysis · doi:10.1038/s41929-020-0450-0 · Cited by 1,468

Density functionals for surface science: Exchange-correlation model development with Bayesian error estimation

Wellendorff, J., Lundgaard, K. T., Møgelhøj, A., Petzold, V., Landis, D. D., Nørskov, J. K., Bligaard, T., & Jacobsen, K. W. (2012) · Physical Review B · doi:10.1103/physrevb.85.235149 · Cited by 1,461

CO 2 electrolysis to multicarbon products in strong acid

Huang, J. E., Li, F., Ozden, A., Sedighian Rasouli, A., García de Arquer, F. P., Liu, S., Zhang, S., Luo, M., Wang, X., Lum, Y., et al. (2021) · Science · doi:10.1126/science.abg6582 · Cited by 1,359

Electrochemical CO 2 Reduction into Chemical Feedstocks: From Mechanistic Electrocatalysis Models to System Design

Kibria, M. G., Edwards, J. P., Gabardo, C. M., Dinh, C., Seifitokaldani, A., Sinton, D., & Sargent, E. H. (2019) · Advanced Materials · doi:10.1002/adma.201807166 · Cited by 1,331

Electrocatalysis for CO 2 conversion: from fundamentals to value-added products

Wang, G., Chen, J., Ding, Y., Cai, P., Yi, L., Li, Y., Tu, C., Hou, Y., Wen, Z., & Dai, L. (2021) · Chemical Society Reviews · doi:10.1039/d0cs00071j · Cited by 1,295

Molecular tuning of CO2-to-ethylene conversion

Li, F., Thevenon, A., Rosas-Hernández, A., Wang, Z., Li, Y., Gabardo, C. M., Ozden, A., Dinh, C. T., Li, J., Wang, Y., et al. (2020) · Nature · doi:10.1038/s41586-019-1782-2 · Cited by 1,275

Highly selective plasma-activated copper catalysts for carbon dioxide reduction to ethylene

Mistry, H., Varela, A. S., Bonifacio, C. S., Zegkinoglou, I., Sinev, I., Choi, Y.-W., Kisslinger, K., Stach, E. A., Yang, J. C., Strasser, P., et al. (2016) · Nature Communications · doi:10.1038/ncomms12123 · Cited by 1,214

Promoter Effects of Alkali Metal Cations on the Electrochemical Reduction of Carbon Dioxide

Resasco, J., Chen, L. D., Clark, E., Tsai, C., Hahn, C., Jaramillo, T. F., Chan, K., & Bell, A. T. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.7b06765 · Cited by 1,184

Electrolytic CO2 Reduction in a Flow Cell

Weekes, D. M., Salvatore, D. A., Reyes, A., Huang, A., & Berlinguette, C. P. (2018) · Accounts of Chemical Research · doi:10.1021/acs.accounts.8b00010 · Cited by 1,067

Catalyst electro-redeposition controls morphology and oxidation state for selective carbon dioxide reduction

De Luna, P., Quintero-Bermudez, R., Dinh, C.-T., Ross, M. B., Bushuyev, O. S., Todorović, P., Regier, T., Kelley, S. O., Yang, P., & Sargent, E. H. (2018) · Nature Catalysis · doi:10.1038/s41929-017-0018-9 · Cited by 1,046

Isolated Ni single atoms in graphene nanosheets for high-performance CO2 reduction

Jiang, K., Siahrostami, S., Zheng, T., Hu, Y., Hwang, S., Stavitski, E., Peng, Y., Dynes, J., Gangisetty, M., Su, D., et al. (2018) · Energy & Environmental Science · doi:10.1039/c7ee03245e · Cited by 1,024

Advances and Challenges for the Electrochemical Reduction of CO2 to CO: From Fundamentals to Industrialization

Jin, S., Hao, Z., Zhang, K., Yan, Z., & Chen, J. (2021) · Angewandte Chemie International Edition · doi:10.1002/anie.202101818 · Cited by 1,022

Absence of CO2 electroreduction on copper, gold and silver electrodes without metal cations in solution

Monteiro, M. C. O., Dattila, F., Hagedoorn, B., García-Muelas, R., López, N., & Koper, M. T. M. (2021) · Nature Catalysis · doi:10.1038/s41929-021-00655-5 · Cited by 1,002

Hydrolysis of Electrolyte Cations Enhances the Electrochemical Reduction of CO 2 over Ag and Cu

Singh, M. R., Kwon, Y., Lum, Y., Ager, J. W., & Bell, A. T. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.6b07612 · Cited by 985

Mechanism of CO2 Reduction at Copper Surfaces: Pathways to C2 Products

Garza, A. J., Bell, A. T., & Head-Gordon, M. (2018) · ACS Catalysis · doi:10.1021/acscatal.7b03477 · Cited by 941

Molecular electrocatalysts can mediate fast, selective CO 2 reduction in a flow cell

Ren, S., Joulié, D., Salvatore, D., Torbensen, K., Wang, M., Robert, M., & Berlinguette, C. P. (2019) · Science · doi:10.1126/science.aax4608 · Cited by 941

In Situ/Operando Electrocatalyst Characterization by X-ray Absorption Spectroscopy

Timoshenko, J., & Roldan Cuenya, B. (2021) · Chemical Reviews · doi:10.1021/acs.chemrev.0c00396 · Cited by 931

Electroreduction of Carbon Dioxide to Hydrocarbons Using Bimetallic Cu–Pd Catalysts with Different Mixing Patterns

Ma, S., Sadakiyo, M., Heima, M., Luo, R., Haasch, R. T., Gold, J. I., Yamauchi, M., & Kenis, P. J. A. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.6b10740 · Cited by 856

Nanoporous Copper–Silver Alloys by Additive-Controlled Electrodeposition for the Selective Electroreduction of CO2 to Ethylene and Ethanol

Hoang, T. T. H., Verma, S., Ma, S., Fister, T. T., Timoshenko, J., Frenkel, A. I., Kenis, P. J. A., & Gewirth, A. A. (2018) · Journal of the American Chemical Society · doi:10.1021/jacs.8b01868 · Cited by 852

Understanding cation effects in electrochemical CO2 reduction

Ringe, S., Clark, E. L., Resasco, J., Walton, A., Seger, B., Bell, A. T., & Chan, K. (2019) · Energy & Environmental Science · doi:10.1039/c9ee01341e · Cited by 848

Modulating electric field distribution by alkali cations for CO2 electroreduction in strongly acidic medium

Gu, J., Liu, S., Ni, W., Ren, W., Haussener, S., & Hu, X. (2022) · Nature Catalysis · doi:10.1038/s41929-022-00761-y · Cited by 846

Metal ion cycling of Cu foil for selective C–C coupling in electrochemical CO2 reduction

Jiang, K., Sandberg, R. B., Akey, A. J., Liu, X., Bell, D. C., Nørskov, J. K., Chan, K., & Wang, H. (2018) · Nature Catalysis · doi:10.1038/s41929-017-0009-x · Cited by 839

Understanding trends in electrochemical carbon dioxide reduction rates

Liu, X., Xiao, J., Peng, H., Hong, X., Chan, K., & Nørskov, J. K. (2017) · Nature Communications · doi:10.1038/ncomms15438 · Cited by 804

Improved CO2 reduction activity towards C2+ alcohols on a tandem gold on copper electrocatalyst

Morales-Guio, C. G., Cave, E. R., Nitopi, S. A., Feaster, J. T., Wang, L., Kuhl, K. P., Jackson, A., Johnson, N. C., Abram, D. N., Hatsukade, T., et al. (2018) · Nature Catalysis · doi:10.1038/s41929-018-0139-9 · Cited by 773

Thermodynamics and kinetics of CO2, CO, and H+ binding to the metal centre of CO2reductioncatalysts

Schneider, J., Jia, H., Muckerman, J. T., & Fujita, E. (2012) · Chem. Soc. Rev. · doi:10.1039/c1cs15278e · Cited by 769

Electrocatalytic reduction of CO2 and CO to multi-carbon compounds over Cu-based catalysts

Ma, W., He, X., Wang, W., Xie, S., Zhang, Q., & Wang, Y. (2021) · Chemical Society Reviews · doi:10.1039/d1cs00535a · Cited by 721

Highly selective electrocatalytic CO2 reduction to ethanol by metallic clusters dynamically formed from atomically dispersed copper

Xu, H., Rebollar, D., He, H., Chong, L., Liu, Y., Liu, C., Sun, C.-J., Li, T., Muntean, J. V., Winans, R. E., et al. (2020) · Nature Energy · doi:10.1038/s41560-020-0666-x · Cited by 710

Electric Field Effects in Electrochemical CO 2 Reduction

Chen, L. D., Urushihara, M., Chan, K., & Nørskov, J. K. (2016) · ACS Catalysis · doi:10.1021/acscatal.6b02299 · Cited by 702

Identification of Possible Pathways for C–C Bond Formation during Electrochemical Reduction of CO 2 : New Theoretical Insights from an Improved Electrochemical Model

Goodpaster, J. D., Bell, A. T., & Head-Gordon, M. (2016) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.6b00358 · Cited by 702

The Central Role of Bicarbonate in the Electrochemical Reduction of Carbon Dioxide on Gold

Dunwell, M., Lu, Q., Heyes, J. M., Rosen, J., Chen, J. G., Yan, Y., Jiao, F., & Xu, B. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.6b13287 · Cited by 700

CO2 Reduction: From Homogeneous to Heterogeneous Electrocatalysis

Zhang, S., Fan, Q., Xia, R., & Meyer, T. J. (2020) · Accounts of Chemical Research · doi:10.1021/acs.accounts.9b00496 · Cited by 682

Defect and Interface Engineering for Aqueous Electrocatalytic CO2 Reduction

Wang, Y., Han, P., Lv, X., Zhang, L., & Zheng, G. (2018) · Joule · doi:10.1016/j.joule.2018.09.021 · Cited by 677

Full atomistic reaction mechanism with kinetics for CO reduction on Cu(100) from ab initio molecular dynamics free-energy calculations at 298 K

Cheng, T., Xiao, H., & Goddard, W. A. (2017) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.1612106114 · Cited by 672

Gas diffusion electrodes and membranes for CO2 reduction electrolysers

Lees, E. W., Mowbray, B. A. W., Parlane, F. G. L., & Berlinguette, C. P. (2021) · Nature Reviews Materials · doi:10.1038/s41578-021-00356-2 · Cited by 664

Theoretical Insights into Heterogeneous (Photo)electrochemical CO2Reduction

Xu, S., & Carter, E. A. (2019) · Chemical Reviews · doi:10.1021/acs.chemrev.8b00481 · Cited by 652

Electrochemical CO2-to-ethylene conversion on polyamine-incorporated Cu electrodes

Chen, X., Chen, J., Alghoraibi, N. M., Henckel, D. A., Zhang, R., Nwabara, U. O., Madsen, K. E., Kenis, P. J. A., Zimmerman, S. C., & Gewirth, A. A. (2020) · Nature Catalysis · doi:10.1038/s41929-020-00547-0 · Cited by 641

High carbon utilization in CO2 reduction to multi-carbon products in acidic media

Xie, Y., Ou, P., Wang, X., Xu, Z., Li, Y. C., Wang, Z., Huang, J. E., Wicks, J., McCallum, C., Wang, N., et al. (2022) · Nature Catalysis · doi:10.1038/s41929-022-00788-1 · Cited by 627

Cu metal embedded in oxidized matrix catalyst to promote CO 2 activation and CO dimerization for electrochemical reduction of CO 2

Xiao, H., Goddard, W. A., Cheng, T., & Liu, Y. (2017) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.1702405114 · Cited by 621

To address surface reaction network complexity using scaling relations machine learning and DFT calculations

Ulissi, Z. W., Medford, A. J., Bligaard, T., & Nørskov, J. K. (2017) · Nature Communications · doi:10.1038/ncomms14621 · Cited by 614

Electrochemical Fragmentation of Cu2O Nanoparticles Enhancing Selective C–C Coupling from CO2 Reduction Reaction

Jung, H., Lee, S. Y., Lee, C. W., Cho, M. K., Won, D. H., Kim, C., Oh, H.-S., Min, B. K., & Hwang, Y. J. (2019) · Journal of the American Chemical Society · doi:10.1021/jacs.8b11237 · Cited by 611

Continuous Carbon Dioxide Electroreduction to Concentrated Multi-carbon Products Using a Membrane Electrode Assembly

Gabardo, C. M., O’Brien, C. P., Edwards, J. P., McCallum, C., Xu, Y., Dinh, C.-T., Li, J., Sargent, E. H., & Sinton, D. (2019) · Joule · doi:10.1016/j.joule.2019.07.021 · Cited by 611

pH effects on the electrochemical reduction of CO(2) towards C2 products on stepped copper

Liu, X., Schlexer, P., Xiao, J., Ji, Y., Wang, L., Sandberg, R. B., Tang, M., Brown, K. S., Peng, H., Ringe, S., et al. (2019) · Nature Communications · doi:10.1038/s41467-018-07970-9 · Cited by 607

Electrochemical CO2 reduction (CO2RR) to multi-carbon products over copper-based catalysts

Woldu, A. R., Huang, Z., Zhao, P., Hu, L., & Astruc, D. (2022) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2021.214340 · Cited by 578

Boosting electrocatalytic CO2–to–ethanol production via asymmetric C–C coupling

Wang, P., Yang, H., Tang, C., Wu, Y., Zheng, Y., Cheng, T., Davey, K., Huang, X., & Qiao, S.-Z. (2022) · Nature Communications · doi:10.1038/s41467-022-31427-9 · Cited by 574

Single-atom catalysts for photocatalytic energy conversion

Xue, Z.-H., Luan, D., Zhang, H., & (David) Lou, X. W. (2022) · Joule · doi:10.1016/j.joule.2021.12.011 · Cited by 567

Revealing the CO Coverage-Driven C–C Coupling Mechanism for Electrochemical CO2 Reduction on Cu2O Nanocubes via Operando Raman Spectroscopy

Zhan, C., Dattila, F., Rettenmaier, C., Bergmann, A., Kühl, S., García-Muelas, R., López, N., & Cuenya, B. R. (2021) · ACS Catalysis · doi:10.1021/acscatal.1c01478 · Cited by 554

Product Selectivity Affected by Cationic Species in Electrochemical Reduction of CO2 and CO at a Cu Electrode

Murata, A., & Hori, Y. (1991) · Bulletin of the Chemical Society of Japan · doi:10.1246/bcsj.64.123 · Cited by 544

Efficient wettability-controlled electroreduction of CO2 to CO at Au/C interfaces

Shi, R., Guo, J., Zhang, X., Waterhouse, G. I. N., Han, Z., Zhao, Y., Shang, L., Zhou, C., Jiang, L., & Zhang, T. (2020) · Nature Communications · doi:10.1038/s41467-020-16847-9 · Cited by 531

Mechanistic Explanation of the pH Dependence and Onset Potentials for Hydrocarbon Products from Electrochemical Reduction of CO on Cu (111)

Xiao, H., Cheng, T., Goddard, W. A., & Sundararaman, R. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.5b11390 · Cited by 527

Insights into the Low Overpotential Electroreduction of CO2 to CO on a Supported Gold Catalyst in an Alkaline Flow Electrolyzer

Verma, S., Hamasaki, Y., Kim, C., Huang, W., Lu, S., Jhong, H.-R. M., Gewirth, A. A., Fujigaya, T., Nakashima, N., & Kenis, P. J. A. (2018) · ACS Energy Letters · doi:10.1021/acsenergylett.7b01096 · Cited by 521

Reaction mechanisms of CO2 electrochemical reduction on Cu(111) determined with density functional theory

Nie, X., Luo, W., Janik, M. J., & Asthagiri, A. (2014) · Journal of Catalysis · doi:10.1016/j.jcat.2014.01.013 · Cited by 510

Modeling gas-diffusion electrodes for CO2 reduction

Weng, L.-C., Bell, A. T., & Weber, A. Z. (2018) · Physical Chemistry Chemical Physics · doi:10.1039/c8cp01319e · Cited by 506

Understanding of Electrochemical Mechanisms for CO2 Capture and Conversion into Hydrocarbon Fuels in Transition-Metal Carbides (MXenes)

Li, N., Chen, X., Ong, W.-J., MacFarlane, D. R., Zhao, X., Cheetham, A. K., & Sun, C. (2017) · ACS Nano · doi:10.1021/acsnano.7b03738 · Cited by 486

Efficient electrocatalytic CO2 reduction on a three-phase interface

Li, J., Chen, G., Zhu, Y., Liang, Z., Pei, A., Wu, C.-L., Wang, H., Lee, H. R., Liu, K., Chu, S., et al. (2018) · Nature Catalysis · doi:10.1038/s41929-018-0108-3 · Cited by 483

Carbon dioxide electroreduction on single-atom nickel decorated carbon membranes with industry compatible current densities

Yang, H., Lin, Q., Zhang, C., Yu, X., Cheng, Z., Li, G., Hu, Q., Ren, X., Zhang, Q., Liu, J., et al. (2020) · Nature Communications · doi:10.1038/s41467-020-14402-0 · Cited by 483

Electrolyte Effects on CO2 Electrochemical Reduction to CO

Marcandalli, G., Monteiro, M. C. O., Goyal, A., & Koper, M. T. M. (2022) · Accounts of Chemical Research · doi:10.1021/acs.accounts.2c00080 · Cited by 480

Time-resolved observation of C–C coupling intermediates on Cu electrodes for selective electrochemical CO2reduction

Kim, Y., Park, S., Shin, S.-J., Choi, W., Min, B. K., Kim, H., Kim, W., & Hwang, Y. J. (2020) · Energy & Environmental Science · doi:10.1039/d0ee01690j · Cited by 479

Electrochemical Barriers Made Simple

Chan, K., & Nørskov, J. K. (2015) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.5b01043 · Cited by 477

Designing anion exchange membranes for CO2 electrolysers

Salvatore, D. A., Gabardo, C. M., Reyes, A., O’Brien, C. P., Holdcroft, S., Pintauro, P., Bahar, B., Hickner, M., Bae, C., Sinton, D., et al. (2021) · Nature Energy · doi:10.1038/s41560-020-00761-x · Cited by 477

Identification of Cu(100)/Cu(111) Interfaces as Superior Active Sites for CO Dimerization During CO2 Electroreduction

Wu, Z.-Z., Zhang, X.-L., Niu, Z.-Z., Gao, F.-Y., Yang, P.-P., Chi, L.-P., Shi, L., Wei, W.-S., Liu, R., Chen, Z., et al. (2022) · Journal of the American Chemical Society · doi:10.1021/jacs.1c09508 · Cited by 471

Structure-Sensitive CO2 Electroreduction to Hydrocarbons on Ultrathin 5-fold Twinned Copper Nanowires

Li, Y., Cui, F., Ross, M. B., Kim, D., Sun, Y., & Yang, P. (2017) · Nano Letters · doi:10.1021/acs.nanolett.6b05287 · Cited by 466

Selective electroreduction of CO2 to acetone by single copper atoms anchored on N-doped porous carbon

Zhao, K., Nie, X., Wang, H., Chen, S., Quan, X., Yu, H., Choi, W., Zhang, G., Kim, B., & Chen, J. G. (2020) · Nature Communications · doi:10.1038/s41467-020-16381-8 · Cited by 464

Electrochemical CO2 reduction to ethylene by ultrathin CuO nanoplate arrays

Liu, W., Zhai, P., Li, A., Wei, B., Si, K., Wei, Y., Wang, X., Zhu, G., Chen, Q., Gu, X., et al. (2022) · Nature Communications · doi:10.1038/s41467-022-29428-9 · Cited by 458

Operando time-resolved X-ray absorption spectroscopy reveals the chemical nature enabling highly selective CO2 reduction

Lin, S.-C., Chang, C.-C., Chiu, S.-Y., Pai, H.-T., Liao, T.-Y., Hsu, C.-S., Chiang, W.-H., Tsai, M.-K., & Chen, H. M. (2020) · Nature Communications · doi:10.1038/s41467-020-17231-3 · Cited by 457

Surface Modification of 2D Photocatalysts for Solar Energy Conversion

Feng, C., Wu, Z., Huang, K., Ye, J., & Zhang, H. (2022) · Advanced Materials · doi:10.1002/adma.202200180 · Cited by 456

Electrochemical Carbon Monoxide Reduction on Polycrystalline Copper: Effects of Potential, Pressure, and pH on Selectivity toward Multicarbon and Oxygenated Products

Wang, L., Nitopi, S. A., Bertheussen, E., Orazov, M., Morales-Guio, C. G., Liu, X., Higgins, D. C., Chan, K., Nørskov, J. K., Hahn, C., et al. (2018) · ACS Catalysis · doi:10.1021/acscatal.8b01200 · Cited by 453

In Situ/Operando Studies for Designing Next-Generation Electrocatalysts

Zhu, Y., Wang, J., Chu, H., Chu, Y.-C., & Chen, H. M. (2020) · ACS Energy Letters · doi:10.1021/acsenergylett.0c00305 · Cited by 450

Rational design of electrocatalytic carbon dioxide reduction for a zero-carbon network

Li, L., Li, X., Sun, Y., & Xie, Y. (2022) · Chemical Society Reviews · doi:10.1039/d1cs00893e · Cited by 448

Sustainion Imidazolium‐Functionalized Polymers for Carbon Dioxide Electrolysis

Kutz, R. B., Chen, Q., Yang, H., Sajjad, S. D., Liu, Z., & Masel, I. R. (2017) · Energy Technology · doi:10.1002/ente.201600636 · Cited by 427

Mechanistic reaction pathways of enhanced ethylene yields during electroreduction of CO2–CO co-feeds on Cu and Cu-tandem electrocatalysts

Wang, X., de Araújo, J. F., Ju, W., Bagger, A., Schmies, H., Kühl, S., Rossmeisl, J., & Strasser, P. (2019) · Nature Nanotechnology · doi:10.1038/s41565-019-0551-6 · Cited by 424

Atypical Oxygen-Bearing Copper Boosts Ethylene Selectivity toward Electrocatalytic CO2 Reduction

Zhang, W., Huang, C., Xiao, Q., Yu, L., Shuai, L., An, P., Zhang, J., Qiu, M., Ren, Z., & Yu, Y. (2020) · Journal of the American Chemical Society · doi:10.1021/jacs.0c01562 · Cited by 414

Structure- and Potential-Dependent Cation Effects on CO Reduction at Copper Single-Crystal Electrodes

Pérez-Gallent, E., Marcandalli, G., Figueiredo, M. C., Calle-Vallejo, F., & Koper, M. T. M. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.7b10142 · Cited by 412

The Role of Cation Acidity on the Competition between Hydrogen Evolution and CO2 Reduction on Gold Electrodes

Monteiro, M. C. O., Dattila, F., López, N., & Koper, M. T. M. (2022) · Journal of the American Chemical Society · doi:10.1021/jacs.1c10171 · Cited by 410

Efficient Electrocatalytic CO2 Reduction to C2+ Alcohols at Defect-Site-Rich Cu Surface

Gu, Z., Shen, H., Chen, Z., Yang, Y., Yang, C., Ji, Y., Wang, Y., Zhu, C., Liu, J., Li, J., et al. (2021) · Joule · doi:10.1016/j.joule.2020.12.011 · Cited by 393

An alkaline polymer electrolyte CO2 electrolyzer operated with pure water

Yin, Z., Peng, H., Wei, X., Zhou, H., Gong, J., Huai, M., Xiao, L., Wang, G., Lu, J., & Zhuang, L. (2019) · Energy & Environmental Science · doi:10.1039/c9ee01204d · Cited by 377

Morphology and mechanism of highly selective Cu(II) oxide nanosheet catalysts for carbon dioxide electroreduction

Wang, X., Klingan, K., Klingenhof, M., Möller, T., Ferreira de Araújo, J., Martens, I., Bagger, A., Jiang, S., Rossmeisl, J., Dau, H., et al. (2021) · Nature Communications · doi:10.1038/s41467-021-20961-7 · Cited by 373

Design strategies for markedly enhancing energy efficiency in the electrocatalytic CO2 reduction reaction

Lai, W., Qiao, Y., Zhang, J., Lin, Z., & Huang, H. (2022) · Energy & Environmental Science · doi:10.1039/d2ee00472k · Cited by 373

Machine learning: Accelerating materials development for energy storage and conversion

Chen, A., Zhang, X., & Zhou, Z. (2020) · InfoMat · doi:10.1002/inf2.12094 · Cited by 370

Multilayer Electrolyzer Stack Converts Carbon Dioxide to Gas Products at High Pressure with High Efficiency

Endrődi, B., Kecsenovity, E., Samu, A., Darvas, F., Jones, R. V., Török, V., Danyi, A., & Janáky, C. (2019) · ACS Energy Letters · doi:10.1021/acsenergylett.9b01142 · Cited by 359

Double sulfur vacancies by lithium tuning enhance CO2 electroreduction to n-propanol

Peng, C., Luo, G., Zhang, J., Chen, M., Wang, Z., Sham, T.-K., Zhang, L., Li, Y., & Zheng, G. (2021) · Nature Communications · doi:10.1038/s41467-021-21901-1 · Cited by 359

Accelerating electrochemical CO2 reduction to multi-carbon products via asymmetric intermediate binding at confined nanointerfaces

Zhang, J., Guo, C., Fang, S., Zhao, X., Li, L., Jiang, H., Liu, Z., Fan, Z., Xu, W., Xiao, J., et al. (2023) · Nature Communications · doi:10.1038/s41467-023-36926-x · Cited by 358

Electrochemical conversion of CO2 to formic acid utilizing Sustainion™ membranes

Yang, H., Kaczur, J. J., Sajjad, S. D., & Masel, R. I. (2017) · Journal of CO2 Utilization · doi:10.1016/j.jcou.2017.04.011 · Cited by 357

Sub‐Second Time‐Resolved Surface‐Enhanced Raman Spectroscopy Reveals Dynamic CO Intermediates during Electrochemical CO2 Reduction on Copper

An, H., Wu, L., Mandemaker, L. D. B., Yang, S., de Ruiter, J., Wijten, J. H. J., Janssens, J. C. L., Hartman, T., van der Stam, W., & Weckhuysen, B. M. (2021) · Angewandte Chemie International Edition · doi:10.1002/anie.202104114 · Cited by 353

Standards and Protocols for Data Acquisition and Reporting for Studies of the Electrochemical Reduction of Carbon Dioxide

Clark, E. L., Resasco, J., Landers, A., Lin, J., Chung, L.-T., Walton, A., Hahn, C., Jaramillo, T. F., & Bell, A. T. (2018) · ACS Catalysis · doi:10.1021/acscatal.8b01340 · Cited by 350

CO-CO coupling on Cu facets: Coverage, strain and field effects

Sandberg, R. B., Montoya, J. H., Chan, K., & Nørskov, J. K. (2016) · Surface Science · doi:10.1016/j.susc.2016.08.006 · Cited by 344

Improved CO2 Electroreduction Performance on Plasma-Activated Cu Catalysts via Electrolyte Design: Halide Effect

Gao, D., Scholten, F., & Roldan Cuenya, B. (2017) · ACS Catalysis · doi:10.1021/acscatal.7b01416 · Cited by 338

Attosecond Electron Dynamics

Kling, M. F., & Vrakking, M. J. J. (2008) · Annual Review of Physical Chemistry · doi:10.1146/annurev.physchem.59.032607.093532 · Cited by 334

Interfacial Electrolyte Effects on Electrocatalytic CO2 Reduction

Deng, B., Huang, M., Zhao, X., Mou, S., & Dong, F. (2022) · ACS Catalysis · doi:10.1021/acscatal.1c03501 · Cited by 326

In Situ Observation of the pH Gradient near the Gas Diffusion Electrode of CO2 Reduction in Alkaline Electrolyte

Lu, X., Zhu, C., Wu, Z., Xuan, J., Francisco, J. S., & Wang, H. (2020) · Journal of the American Chemical Society · doi:10.1021/jacs.0c06779 · Cited by 314

Toward solar-driven carbon recycling

Lin, H., Luo, S., Zhang, H., & Ye, J. (2022) · Joule · doi:10.1016/j.joule.2022.01.001 · Cited by 313

Effects of Surface Roughness on the Electrochemical Reduction of CO2 over Cu

Jiang, K., Huang, Y., Zeng, G., Toma, F. M., Goddard, W. A., & Bell, A. T. (2020) · ACS Energy Letters · doi:10.1021/acsenergylett.0c00482 · Cited by 311

Emerging dynamic structure of electrocatalysts unveiled by in situ X-ray diffraction/absorption spectroscopy

Zhu, Y., Kuo, T.-R., Li, Y.-H., Qi, M.-Y., Chen, G., Wang, J., Xu, Y.-J., & Chen, H. M. (2021) · Energy & Environmental Science · doi:10.1039/d0ee03903a · Cited by 308

Optimizing the Electrocatalytic Selectivity of Carbon Dioxide Reduction Reaction by Regulating the Electronic Structure of Single‐Atom M‐N‐C Materials

Tang, T., Wang, Z., & Guan, J. (2022) · Advanced Functional Materials · doi:10.1002/adfm.202111504 · Cited by 304

Operando characterization techniques for electrocatalysis

Li, J., & Gong, J. (2020) · Energy & Environmental Science · doi:10.1039/d0ee01706j · Cited by 290

Recovering carbon losses in CO2 electrolysis using a solid electrolyte reactor

Kim, J. Y. ‘., Zhu, P., Chen, F.-Y., Wu, Z.-Y., Cullen, D. A., & Wang, H. (2022) · Nature Catalysis · doi:10.1038/s41929-022-00763-w · Cited by 282

Long-chain hydrocarbons by CO2 electroreduction using polarized nickel catalysts

Zhou, Y., Martín, A. J., Dattila, F., Xi, S., López, N., Pérez-Ramírez, J., & Yeo, B. S. (2022) · Nature Catalysis · doi:10.1038/s41929-022-00803-5 · Cited by 277

Free-Energy Barriers and Reaction Mechanisms for the Electrochemical Reduction of CO on the Cu(100) Surface, Including Multiple Layers of Explicit Solvent at pH 0

Cheng, T., Xiao, H., & Goddard, W. A. (2015) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.5b02247 · Cited by 272

Advances and Challenges for the Electrochemical Reduction of CO2 to CO: From Fundamentals to Industrialization

Jin, S., Hao, Z., Zhang, K., Yan, Z., & Chen, J. (2021) · Angewandte Chemie · doi:10.1002/ange.202101818 · Cited by 272

A Surface Reconstruction Route to High Productivity and Selectivity in CO2 Electroreduction toward C2+ Hydrocarbons

Kibria, M. G., Dinh, C., Seifitokaldani, A., De Luna, P., Burdyny, T., Quintero‐Bermudez, R., Ross, M. B., Bushuyev, O. S., García de Arquer, F. P., Yang, P., et al. (2018) · Advanced Materials · doi:10.1002/adma.201804867 · Cited by 269

Coverage-driven selectivity switch from ethylene to acetate in high-rate CO2/CO electrolysis

Wei, P., Gao, D., Liu, T., Li, H., Sang, J., Wang, C., Cai, R., Wang, G., & Bao, X. (2023) · Nature Nanotechnology · doi:10.1038/s41565-022-01286-y · Cited by 264

Engineering the Coordination Sphere of Isolated Active Sites to Explore the Intrinsic Activity in Single-Atom Catalysts

Wu, X., Zhang, H., Zuo, S., Dong, J., Li, Y., Zhang, J., & Han, Y. (2021) · Nano-Micro Letters · doi:10.1007/s40820-021-00668-6 · Cited by 261

Effects of Anion Identity and Concentration on Electrochemical Reduction of CO 2

Resasco, J., Lum, Y., Clark, E., Zeledon, J. Z., & Bell, A. T. (2018) · ChemElectroChem · doi:10.1002/celc.201701316 · Cited by 250

In-situ liquid cell transmission electron microscopy investigation on oriented attachment of gold nanoparticles

Zhu, C., Liang, S., Song, E., Zhou, Y., Wang, W., Shan, F., Shi, Y., Hao, C., Yin, K., Zhang, T., et al. (2018) · Nature Communications · doi:10.1038/s41467-018-02925-6 · Cited by 249

Intermediate Binding Control Using Metal–Organic Frameworks Enhances Electrochemical CO2 Reduction

Nam, D.-H., Shekhah, O., Lee, G., Mallick, A., Jiang, H., Li, F., Chen, B., Wicks, J., Eddaoudi, M., & Sargent, E. H. (2020) · Journal of the American Chemical Society · doi:10.1021/jacs.0c10774 · Cited by 246

In situ dual doping for constructing efficient CO2-to-methanol electrocatalysts

Li, P., Bi, J., Liu, J., Zhu, Q., Chen, C., Sun, X., Zhang, J., & Han, B. (2022) · Nature Communications · doi:10.1038/s41467-022-29698-3 · Cited by 241

Selective CO2reduction to C3and C4oxyhydrocarbons on nickel phosphides at overpotentials as low as 10 mV

Calvinho, K. U. D., Laursen, A. B., Yap, K. M. K., Goetjen, T. A., Hwang, S., Murali, N., Mejia-Sosa, B., Lubarski, A., Teeluck, K. M., Hall, E. S., et al. (2018) · Energy & Environmental Science · doi:10.1039/c8ee00936h · Cited by 239

Quaternized aryl ether-free polyaromatics for alkaline membrane fuel cells: synthesis, properties, and performance – a topical review

Park, E. J., & Kim, Y. S. (2018) · Journal of Materials Chemistry A · doi:10.1039/c8ta05428b · Cited by 239

The role of electrode wettability in electrochemical reduction of carbon dioxide

Li, M., Idros, M. N., Wu, Y., Burdyny, T., Garg, S., Zhao, X. S., Wang, G., & Rufford, T. E. (2021) · Journal of Materials Chemistry A · doi:10.1039/d1ta03636j · Cited by 239

Theoretical Considerations on the Electroreduction of CO to C2 Species on Cu(100) Electrodes

Calle‐Vallejo, F., & Koper, M. T. M. (2013) · Angewandte Chemie · doi:10.1002/ange.201301470 · Cited by 239

Effects of composition of the micro porous layer and the substrate on performance in the electrochemical reduction of CO2 to CO

Kim, B., Hillman, F., Ariyoshi, M., Fujikawa, S., & Kenis, P. J. A. (2016) · Journal of Power Sources · doi:10.1016/j.jpowsour.2016.02.043 · Cited by 238

Close to 90% Single-Pass Conversion Efficiency for CO2 Electroreduction in an Acid-Fed Membrane Electrode Assembly

Pan, B., Fan, J., Zhang, J., Luo, Y., Shen, C., Wang, C., Wang, Y., & Li, Y. (2022) · ACS Energy Letters · doi:10.1021/acsenergylett.2c02292 · Cited by 236

Oxygen Vacancy Tuning toward Efficient Electrocatalytic CO2 Reduction to C2H4

Gu, Z., Yang, N., Han, P., Kuang, M., Mei, B., Jiang, Z., Zhong, J., Li, L., & Zheng, G. (2019) · Small Methods · doi:10.1002/smtd.201800449 · Cited by 234

Implanting Isolated Ru Atoms into Edge‐Rich Carbon Matrix for Efficient Electrocatalytic Hydrogen Evolution

Zhang, H., Zhou, W., Lu, X. F., Chen, T., & Lou, X. W. (. (2020) · Advanced Energy Materials · doi:10.1002/aenm.202000882 · Cited by 233

Beyond the catalyst: How electrode and reactor design determine the product spectrum during electrochemical CO2 reduction

Vennekoetter, J.-B., Sengpiel, R., & Wessling, M. (2019) · Chemical Engineering Journal · doi:10.1016/j.cej.2019.01.045 · Cited by 230

Atomic Layer Deposition of ZnO on CuO Enables Selective and Efficient Electroreduction of Carbon Dioxide to Liquid Fuels

Ren, D., Gao, J., Pan, L., Wang, Z., Luo, J., Zakeeruddin, S. M., Hagfeldt, A., & Grätzel, M. (2019) · Angewandte Chemie International Edition · doi:10.1002/anie.201909610 · Cited by 229

Engineering a conductive network of atomically thin bismuthene with rich defects enables CO2 reduction to formate with industry-compatible current densities and stability

Zhang, M., Wei, W., Zhou, S., Ma, D.-D., Cao, A., Wu, X.-T., & Zhu, Q.-L. (2021) · Energy & Environmental Science · doi:10.1039/d1ee01495a · Cited by 224

Recent Advances on Transition Metal Dichalcogenides for Electrochemical Energy Conversion

Wu, X., Zhang, H., Zhang, J., & Lou, X. W. (. (2021) · Advanced Materials · doi:10.1002/adma.202008376 · Cited by 224

Engineering Water Molecules Activation Center on Multisite Electrocatalysts for Enhanced CO2 Methanation

Chen, S., Zhang, Z., Jiang, W., Zhang, S., Zhu, J., Wang, L., Ou, H., Zaman, S., Tan, L., Zhu, P., et al. (2022) · Journal of the American Chemical Society · doi:10.1021/jacs.2c03875 · Cited by 224

Plasmonic photosynthesis of C1–C3 hydrocarbons from carbon dioxide assisted by an ionic liquid

Yu, S., & Jain, P. K. (2019) · Nature Communications · doi:10.1038/s41467-019-10084-5 · Cited by 220

Operando Monitoring and Deciphering the Structural Evolution in Oxygen Evolution Electrocatalysis

Zuo, S., Wu, Z., Zhang, H., & Lou, X. W. (. (2022) · Advanced Energy Materials · doi:10.1002/aenm.202103383 · Cited by 217

Liquid Fluxional Ga Single Atom Catalysts for Efficient Electrochemical CO2Reduction

Zhang, Z., Zhu, J., Chen, S., Sun, W., & Wang, D. (2023) · Angewandte Chemie International Edition · doi:10.1002/anie.202215136 · Cited by 215

Dynamic Evolution of Active Sites in Electrocatalytic CO2 Reduction Reaction: Fundamental Understanding and Recent Progress

Lai, W., Ma, Z., Zhang, J., Yuan, Y., Qiao, Y., & Huang, H. (2022) · Advanced Functional Materials · doi:10.1002/adfm.202111193 · Cited by 213

A Machine Learning Model on Simple Features for CO2 Reduction Electrocatalysts

Chen, A., Zhang, X., Chen, L., Yao, S., & Zhou, Z. (2020) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.0c05964 · Cited by 207

Selectivity of CO2 Reduction on Copper Electrodes: The Role of the Kinetics of Elementary Steps

Nie, X., Esopi, M. R., Janik, M. J., & Asthagiri, A. (2013) · Angewandte Chemie · doi:10.1002/ange.201208320 · Cited by 207

Highly Ethylene‐Selective Electrocatalytic CO2 Reduction Enabled by Isolated Cu−S Motifs in Metal–Organic Framework Based Precatalysts

Wen, C. F., Zhou, M., Liu, P. F., Liu, Y., Wu, X., Mao, F., Dai, S., Xu, B., Wang, X. L., Jiang, Z., et al. (2022) · Angewandte Chemie International Edition · doi:10.1002/anie.202111700 · Cited by 206

A general synthesis of single atom catalysts with controllable atomic and mesoporous structures

Wu, Z.-Y., Zhu, P., Cullen, D. A., Hu, Y., Yan, Q.-Q., Shen, S.-C., Chen, F.-Y., Yu, H., Shakouri, M., Arregui-Mena, J. D., et al. (2022) · Nature Synthesis · doi:10.1038/s44160-022-00129-x · Cited by 206

Atomically Dispersed Reactive Centers for Electrocatalytic CO2 Reduction and Water Splitting

Zhang, H., Cheng, W., Luan, D., & Lou, X. W. (. (2021) · Angewandte Chemie International Edition · doi:10.1002/anie.202014112 · Cited by 201

Unraveling the rate-limiting step of two-electron transfer electrochemical reduction of carbon dioxide

Deng, W., Zhang, P., Seger, B., & Gong, J. (2022) · Nature Communications · doi:10.1038/s41467-022-28436-z · Cited by 201

Stabilizing copper sites in coordination polymers toward efficient electrochemical C-C coupling

Liang, Y., Zhao, J., Yang, Y., Hung, S.-F., Li, J., Zhang, S., Zhao, Y., Zhang, A., Wang, C., Appadoo, D., et al. (2023) · Nature Communications · doi:10.1038/s41467-023-35993-4 · Cited by 200

Molecular Engineering of Hydroxide Conducting Polymers for Anion Exchange Membranes in Electrochemical Energy Conversion Technology

Noh, S., Jeon, J. Y., Adhikari, S., Kim, Y. S., & Bae, C. (2019) · Accounts of Chemical Research · doi:10.1021/acs.accounts.9b00355 · Cited by 199

Rational design of three-phase interfaces for electrocatalysis

Wang, Y., Zou, Y., Tao, L., Wang, Y., Huang, G., Du, S., & Wang, S. (2019) · Nano Research · doi:10.1007/s12274-019-2310-2 · Cited by 196

Impact of Pulsed Electrochemical Reduction of CO2 on the Formation of C2+ Products over Cu

Kim, C., Weng, L.-C., & Bell, A. T. (2020) · ACS Catalysis · doi:10.1021/acscatal.0c02915 · Cited by 193

Enhanced Electrocatalytic CO2 Reduction to C2+ Products by Adjusting the Local Reaction Environment with Polymer Binders

Pham, T. H. M., Zhang, J., Li, M., Shen, T., Ko, Y., Tileli, V., Luo, W., & Züttel, A. (2022) · Advanced Energy Materials · doi:10.1002/aenm.202103663 · Cited by 193

Cu-based bimetallic electrocatalysts for CO2 reduction

Jia, Y., Li, F., Fan, K., & Sun, L. (2022) · Advanced Powder Materials · doi:10.1016/j.apmate.2021.10.003 · Cited by 191

Bi2O3/BiO2 Nanoheterojunction for Highly Efficient Electrocatalytic CO2 Reduction to Formate

Feng, X., Zou, H., Zheng, R., Wei, W., Wang, R., Zou, W., Lim, G., Hong, J., Duan, L., & Chen, H. (2022) · Nano Letters · doi:10.1021/acs.nanolett.1c04683 · Cited by 190

An Investigation of Active Sites for electrochemical CO2 Reduction Reactions: From In Situ Characterization to Rational Design

Zou, Y., & Wang, S. (2021) · Advanced Science · doi:10.1002/advs.202003579 · Cited by 189

Barriers of Electrochemical CO2 Reduction on Transition Metals

Shi, C., Chan, K., Yoo, J. S., & Nørskov, J. K. (2016) · Organic Process Research & Development · doi:10.1021/acs.oprd.6b00103 · Cited by 184

A Stable and Conductive Covalent Organic Framework with Isolated Active Sites for Highly Selective Electroreduction of Carbon Dioxide to Acetate

Qiu, X., Huang, J., Yu, C., Zhao, Z., Zhu, H., Ke, Z., Liao, P., & Chen, X. (2022) · Angewandte Chemie International Edition · doi:10.1002/anie.202206470 · Cited by 184

Oxygen induced promotion of electrochemical reduction of CO2 via co-electrolysis

He, M., Li, C., Zhang, H., Chang, X., Chen, J. G., Goddard, W. A., Cheng, M.-J., Xu, B., & Lu, Q. (2020) · Nature Communications · doi:10.1038/s41467-020-17690-8 · Cited by 183

Rigorous assessment of CO2 electroreduction products in a flow cell

Niu, Z.-Z., Chi, L.-P., Liu, R., Chen, Z., & Gao, M.-R. (2021) · Energy & Environmental Science · doi:10.1039/d1ee01664d · Cited by 181

Covalently anchoring covalent organic framework on carbon nanotubes for highly efficient electrocatalytic CO2 reduction

Dong, H., Lu, M., Wang, Y., Tang, H.-L., Wu, D., Sun, X., & Zhang, F.-M. (2022) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2021.120897 · Cited by 178

Structural Reconstruction of Cu2O Superparticles toward Electrocatalytic CO2 Reduction with High C2+ Products Selectivity

Jiang, Y., Wang, X., Duan, D., He, C., Ma, J., Zhang, W., Liu, H., Long, R., Li, Z., Kong, T., et al. (2022) · Advanced Science · doi:10.1002/advs.202105292 · Cited by 177

Comprehensive Mechanism of CO2 Electroreduction toward Ethylene and Ethanol: The Solvent Effect from Explicit Water–Cu(100) Interface Models

Santatiwongchai, J., Faungnawakij, K., & Hirunsit, P. (2021) · ACS Catalysis · doi:10.1021/acscatal.1c01486 · Cited by 173

Steering surface reconstruction of copper with electrolyte additives for CO2 electroreduction

Han, Z., Han, D., Chen, Z., Gao, J., Jiang, G., Wang, X., Lyu, S., Guo, Y., Geng, C., Yin, L., et al. (2022) · Nature Communications · doi:10.1038/s41467-022-30819-1 · Cited by 173

High‐Rate and Selective CO2 Electrolysis to Ethylene via Metal–Organic‐Framework‐Augmented CO2 Availability

Nam, D., Shekhah, O., Ozden, A., McCallum, C., Li, F., Wang, X., Lum, Y., Lee, T., Li, J., Wicks, J., et al. (2022) · Advanced Materials · doi:10.1002/adma.202207088 · Cited by 172

In Situ Halogen‐Ion Leaching Regulates Multiple Sites on Tandem Catalysts for Efficient CO2 Electroreduction to C2+ Products

Yang, R., Duan, J., Dong, P., Wen, Q., Wu, M., Liu, Y., Liu, Y., Li, H., & Zhai, T. (2022) · Angewandte Chemie International Edition · doi:10.1002/anie.202116706 · Cited by 171

Effects of Electrolyte Anions on the Reduction of Carbon Dioxide to Ethylene and Ethanol on Copper (100) and (111) Surfaces

Huang, Y., Ong, C. W., & Yeo, B. S. (2018) · ChemSusChem · doi:10.1002/cssc.201801078 · Cited by 170

Au-activated N motifs in non-coherent cupric porphyrin metal organic frameworks for promoting and stabilizing ethylene production

Xie, X., Zhang, X., Xie, M., Xiong, L., Sun, H., Lu, Y., Mu, Q., Rummeli, M. H., Xu, J., Li, S., et al. (2022) · Nature Communications · doi:10.1038/s41467-021-27768-6 · Cited by 168

Enhanced electroreduction of CO2 to C2+ products on heterostructured Cu/oxide electrodes

Li, X., Liu, Q., Wang, J., Meng, D., Shu, Y., Lv, X., Zhao, B., Yang, H., Cheng, T., Gao, Q., et al. (2022) · Chem · doi:10.1016/j.chempr.2022.04.004 · Cited by 167

Two‐Dimensional Metal–Organic Frameworks and Covalent–Organic Frameworks for Electrocatalysis: Distinct Merits by the Reduced Dimension

Lee, M. K., Shokouhimehr, M., Kim, S. Y., & Jang, H. W. (2022) · Advanced Energy Materials · doi:10.1002/aenm.202003990 · Cited by 166

Electrocatalytic Reduction of CO2 to Acetic Acid by a Molecular Manganese Corrole Complex

De, R., Gonglach, S., Paul, S., Haas, M., Sreejith, S. S., Gerschel, P., Apfel, U., Vuong, T. H., Rabeah, J., Roy, S., et al. (2020) · Angewandte Chemie International Edition · doi:10.1002/anie.202000601 · Cited by 164

Revisiting Understanding of Electrochemical CO 2 Reduction on Cu(111): Competing Proton-Coupled Electron Transfer Reaction Mechanisms Revealed by Embedded Correlated Wavefunction Theory

Zhao, Q. X., Martirez, J. M. P., & Carter, E. A. (2021) · Journal of the American Chemical Society · doi:10.1021/jacs.1c00880 · Cited by 164

Modeling Operando Electrochemical CO 2 Reduction

Dattila, F., Seemakurthi, R. R., Zhou, Y., & López, N. (2022) · Chemical Reviews · doi:10.1021/acs.chemrev.1c00690 · Cited by 162

Dual Role of Pyridinic-N Doping in Carbon-Coated Ni Nanoparticles for Highly Efficient Electrochemical CO2 Reduction to CO over a Wide Potential Range

Lu, Q., Chen, C., Di, Q., Liu, W., Sun, X., Tuo, Y., Zhou, Y., Pan, Y., Feng, X., Li, L., et al. (2022) · ACS Catalysis · doi:10.1021/acscatal.1c04825 · Cited by 161

Electrochemical CO 2 Reduction Reaction on M@Cu(211) Bimetallic Single-Atom Surface Alloys: Mechanism, Kinetics, and Catalyst Screening

Feng, Y., An, W., Wang, Z., Wang, Y., Men, Y., & Du, Y. (2019) · ACS Sustainable Chemistry & Engineering · doi:10.1021/acssuschemeng.9b05183 · Cited by 158

In‐Situ Nanostructuring and Stabilization of Polycrystalline Copper by an Organic Salt Additive Promotes Electrocatalytic CO 2 Reduction to Ethylene

Thevenon, A., Rosas‐Hernández, A., Peters, J. C., & Agapie, T. (2019) · Angewandte Chemie International Edition · doi:10.1002/anie.201907935 · Cited by 155

Synthesis of amino acids by electrocatalytic reduction of CO2 on chiral Cu surfaces

Fang, Y., Liu, X., Liu, Z., Han, L., Ai, J., Zhao, G., Terasaki, O., Cui, C., Yang, J., Liu, C., et al. (2022) · Chem · doi:10.1016/j.chempr.2022.10.017 · Cited by 155

Effects of Electrolyte Buffer Capacity on Surface Reactant Species and the Reaction Rate of CO 2 in Electrochemical CO 2 Reduction

Hashiba, H., Weng, L., Chen, Y., Sato, H., Yotsuhashi, S., Xiang, C., & Weber, A. Z. (2018) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.7b11316 · Cited by 152

The product selectivity zones in gas diffusion electrodes during the electrocatalytic reduction of CO 2

Möller, T., Thanh, T. N., Wang, X., Ju, W., Jovanov, Z. P., & Strasser, P. (2021) · Energy & Environmental Science · doi:10.1039/d1ee01696b · Cited by 151

Applications of Metal–Organic Frameworks and Their Derivatives in Electrochemical CO2 Reduction

Li, C., Ji, Y., Wang, Y., Liu, C., Chen, Z., Tang, J., Hong, Y., Li, X., Zheng, T., Jiang, Q. M., et al. (2023) · Nano-Micro Letters · doi:10.1007/s40820-023-01092-8 · Cited by 151

Grain-Boundary-Engineered La 2 CuO 4 Perovskite Nanobamboos for Efficient CO 2 Reduction Reaction

Wang, J., Cheng, C., Huang, B., Cao, J., Li, L., Shao, Q., Zhang, L., & Huang, X. (2021) · Nano Letters · doi:10.1021/acs.nanolett.0c04004 · Cited by 150

Guiding CO2RR Selectivity by Compositional Tuning in the Electrochemical Double Layer

Banerjee, S., Gerke, C. S., & Thoi, V. S. (2022) · Accounts of Chemical Research · doi:10.1021/acs.accounts.1c00680 · Cited by 148

A microchanneled solid electrolyte for carbon-efficient CO2 electrolysis

Xu, Y., Miao, R. K., Edwards, J. P., Liu, S., O’Brien, C. P., Gabardo, C. M., Fan, M., Huang, J. E., Robb, A., Sargent, E. H., et al. (2022) · Joule · doi:10.1016/j.joule.2022.04.023 · Cited by 148

In‐Situ Constructuring of Copper‐Doped Bismuth Catalyst for Highly Efficient CO 2 Electrolysis to Formate in Ampere‐Level

Shen, H., Zhao, Y., Zhang, L., He, Y., Yang, S., Wang, T., Cao, Y., Guo, Y., Zhang, Q., & Zhang, H. (2022) · Advanced Energy Materials · doi:10.1002/aenm.202202818 · Cited by 147

Cation-Coordinated Inner-Sphere CO 2 Electroreduction at Au–Water Interfaces

Qin, X., Vegge, T., & Hansen, H. A. (2023) · Journal of the American Chemical Society · doi:10.1021/jacs.2c11643 · Cited by 147

Flexible Cuprous Triazolate Frameworks as Highly Stable and Efficient Electrocatalysts for CO 2 Reduction with Tunable C 2 H 4 /CH 4 Selectivity

Zhuo, L., Chen, P., Zheng, K., Zhang, X., Wu, J., Lin, D., Liu, S., Wang, Z., Liu, J., Zhou, D., et al. (2022) · Angewandte Chemie International Edition · doi:10.1002/anie.202204967 · Cited by 145

Proton sponge promotion of electrochemical CO2 reduction to multi-carbon products

Fan, L., Liu, C.-Y., Zhu, P., Xia, C., Zhang, X., Wu, Z., Lü, Y., Senftle, T. P., & Wang, H. (2021) · Joule · doi:10.1016/j.joule.2021.12.002 · Cited by 143

Potential of MXene-Based Heterostructures for Energy Conversion and Storage

Pang, J., Chang, B., Liu, H., & Zhou, W. (2021) · ACS Energy Letters · doi:10.1021/acsenergylett.1c02132 · Cited by 143

A New Hexagonal Cobalt Nanosheet Catalyst for Selective CO2 Conversion to Ethanal

Yin, J., Yin, Z., Jin, J., Sun, M., Huang, B., Lin, H., Ma, Z., Muzzio, M., Shen, M., Yu, C., et al. (2021) · Journal of the American Chemical Society · doi:10.1021/jacs.1c06877 · Cited by 142

Enabling heterogeneous catalysis to achieve carbon neutrality: Directional catalytic conversion of CO 2 into carboxylic acids

Zhang, X., Huang, W., Yu, L., Melchor, M. G., Wang, D. S., Zhi, L., & Zhang, H. (2023) · Carbon Energy · doi:10.1002/cey2.362 · Cited by 142

Opportunities for Electrocatalytic CO 2 Reduction Enabled by Surface Ligands

Zhu, Q., Murphy, C. J., & Baker, L. R. (2022) · Journal of the American Chemical Society · doi:10.1021/jacs.1c11500 · Cited by 141

Shaping Copper Nanocatalysts to Steer Selectivity in the Electrochemical CO2 Reduction Reaction

Rossi, K., & Buonsanti, R. (2022) · Accounts of Chemical Research · doi:10.1021/acs.accounts.1c00673 · Cited by 141

Product-Specific Active Site Motifs of Cu for Electrochemical CO2 Reduction

Zhu, C., Zhang, Z., Zhong, L., Hsu, C., Xu, X., Li, Y., Zhao, S., Chen, S., Yu, J. J., Chen, S., et al. (2020) · Chem · doi:10.1016/j.chempr.2020.10.018 · Cited by 140

Potential-Dependent Free Energy Relationship in Interpreting the Electrochemical Performance of CO 2 Reduction on Single Atom Catalysts

Cao, H., Zhang, Z., Chen, J., & Wang, Y. (2022) · ACS Catalysis · doi:10.1021/acscatal.2c01470 · Cited by 132

Time-Resolved Local pH Measurements during CO 2 Reduction Using Scanning Electrochemical Microscopy: Buffering and Tip Effects

Monteiro, M. C. O., Mirabal, A., Jacobse, L., Doblhoff-Dier, K., Barton, S. C., & Koper, M. T. M. (2021) · JACS Au · doi:10.1021/jacsau.1c00289 · Cited by 131

Hierarchical micro/nanostructured silver hollow fiber boosts electroreduction of carbon dioxide

Li, S., Chen, W., Dong, X., Zhu, C., Chen, A., Song, Y., Li, G., Wei, W., & Sun, Y. (2022) · Nature Communications · doi:10.1038/s41467-022-30733-6 · Cited by 128

In Situ Characterization for Boosting Electrocatalytic Carbon Dioxide Reduction

Cao, X., Tan, D., Wulan, B., Hui, K. S., Hui, K. S., & Zhang, J. (2021) · Small Methods · doi:10.1002/smtd.202100700 · Cited by 125

Highly Selective Two‐Electron Electrocatalytic CO2 Reduction on Single‐Atom Cu Catalysts

Xu, C., Zhi, X., Vasileff, A., Wang, D., Jin, B., Jiao, Y., Zheng, Y., & Qiao, S. (2020) · Small Structures · doi:10.1002/sstr.202000058 · Cited by 124

Promotional Role of a Cation Intermediate Complex in C 2 Formation from Electrochemical Reduction of CO 2 over Cu

Liu, H., Liu, J., & Yang, B. (2021) · ACS Catalysis · doi:10.1021/acscatal.1c01072 · Cited by 124

Bimetallic Cu–Zn Catalysts for Electrochemical CO 2 Reduction: Phase-Separated versus Core–Shell Distribution

Wan, L., Zhang, X., Cheng, J., Chen, R., Wu, L., Shi, J., & Luo, J. (2022) · ACS Catalysis · doi:10.1021/acscatal.1c05272 · Cited by 124

Enhancing Selective Electrochemical CO 2 Reduction by In Situ Constructing Tensile-Strained Cu Catalysts

Wei, Z., Ding, J., Duan, X., Chen, G.-L., Wu, F., Zhang, L., Yang, X., Zhang, Q., He, Q., Chen, Z., et al. (2023) · ACS Catalysis · doi:10.1021/acscatal.3c00181 · Cited by 123

A Metal–Organic Framework derived CuxOyCz Catalyst for Electrochemical CO2 Reduction and Impact of Local pH Change

Sikdar, N., Junqueira, J. R. C., Dieckhöfer, S., Quast, T., Braun, M., Song, Y., Aiyappa, H. B., Seisel, S., Weidner, J., Öhl, D., et al. (2021) · Angewandte Chemie International Edition · doi:10.1002/anie.202108313 · Cited by 121

Grain refining enables mixed Cu+/Cu0 states for CO2 electroreduction to C2+ products at high current density

Lv, X., Liu, Q., Wang, J., Wu, X., Li, X., Yang, Y., Yan, J., Wu, A., & Wu, H. B. (2022) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2022.122272 · Cited by 121

Local pH Effect in the CO2Reduction Reaction on High-Surface-Area Copper Electrocatalysts

Raciti, D., Mao, M., Park, J. H., & Wang, C. (2018) · Journal of The Electrochemical Society · doi:10.1149/2.0521810jes · Cited by 119

Protecting the state of Cu clusters and nanoconfinement engineering over hollow mesoporous carbon spheres for electrocatalytical C-C coupling

Pan, Y., Li, H., Xiong, J., Yu, Y., Du, H., Li, S., Wu, Z., Li, S., Lai, J., & Wang, L. (2022) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2022.121111 · Cited by 119

Superscalar Phase Boundaries Derived Multiple Active Sites in SnO2/Cu6Sn5/CuO for Tandem Electroreduction of CO2 to Formic Acid

Shi, Y., Wang, Y., Yu, J., Chen, Y., Fang, C., Jiang, D., Zhang, Q., Gu, L., Yu, X., Li, X., et al. (2023) · Advanced Energy Materials · doi:10.1002/aenm.202203506 · Cited by 119

Anchoring Ionic Liquid in Copper Electrocatalyst for Improving CO2 Conversion to Ethylene

Sha, Y., Zhang, J., Cheng, X., Xu, M., Su, Z., Wang, Y., Hu, J., Han, B., & Zheng, L. (2022) · Angewandte Chemie International Edition · doi:10.1002/anie.202200039 · Cited by 113

Computational Screening of Single and Di-Atom Catalysts for Electrochemical CO 2 Reduction

Karmodak, N., Vijay, S., Kastlunger, G., & Chan, K. (2022) · ACS Catalysis · doi:10.1021/acscatal.1c05750 · Cited by 112

A machine learning scheme for the catalytic activity of alloys with intrinsic descriptors

Yang, Z. K., Gao, W., & Jiang, Q. (2020) · Journal of Materials Chemistry A · doi:10.1039/d0ta06203k · Cited by 110

Insertion of MXene‐Based Materials into Cu–Pd 3D Aerogels for Electroreduction of CO 2 to Formate

Abdinejad, M., Subramanian, S., Khorasani-Motlagh, M., Noroozifar, M., Duangdangchote, S., Neporozhnii, I., Ripepi, D., Pinto, D., Li, M., Tang, K., et al. (2023) · Advanced Energy Materials · doi:10.1002/aenm.202300402 · Cited by 110

Immobilized trimeric metal clusters: A family of the smallest catalysts for selective CO2 reduction toward multi-carbon products

Pei, W., Zhou, S., Zhao, J., Xu, X., Du, Y., & Dou, S. X. (2020) · Nano Energy · doi:10.1016/j.nanoen.2020.105049 · Cited by 108

Single atom-based catalysts for electrochemical CO2 reduction

Sun, Q., Jia, C., Zhao, Y. S., & Zhao, C. (2022) · CHINESE JOURNAL OF CATALYSIS (CHINESE VERSION) · doi:10.1016/s1872-2067(21)64000-7 · Cited by 108

Selective synthesis of butane from carbon monoxide using cascade electrolysis and thermocatalysis at ambient conditions

Lee‬, M. G., Li, X., Ozden, A., Wicks, J., Ou, P., Li, Y., Dorakhan, R., Lee, J., Park, H. K., Yang, J. W., et al. (2023) · Nature Catalysis · doi:10.1038/s41929-023-00937-0 · Cited by 108